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The Pharmaceutical Journal Vol 265 No 7118 p536
October 14, 2000 Onlooker

Foiling the witch

Witch bottles are intriguing objects, which now and then turn up when ancient cottages are being renovated. They were prepared in the 17th century by people who thought they were being spellbound by a witch and wanted to counteract the evil. The essential ingredient of the contents of a witch bottle was urine from the victim of the spell, placed in a bottle or earthenware jar with thorns, pins or nails — objects of penetrating nature that were believed to inflict severe pain on the witch if he or she tried to urinate.
In Current Archaeology for August is an account of an intact witch bottle retrieved in 1993 from the ruins of a cottage in Reigate that had been demolished some 250 years ago. There is evidence that although the green glass bottle probably dates from about 1685 it was deposited later than 1720. Analysis of its contents revealed sodium, potassium, calcium, magnesium, chloride, sulphate, phosphate and nitrate, without significant organic residue. The high nitrate content was attributed to the former presence of urine, whose urea had been converted into carbon dioxide and ammonia and later into nitrate, a reaction exploited by former gunpowder manufacturers.
Within the bottle were nine brass pins, evidently bent into an L-shape as a single bunch. Traces of black pigment on these proved to be copper sulphide, and there were also patches of calcium phosphate. The sulphide was supposed to be derived from urinary alkylsulphate, cysteine and methionine. A brownish deposit proved to consist of calcite, silica and calcium phosphate. Fragments of cotton fibre were identified by microscopy, some showing traces of black, blue and pink-red dyes. Also detected were wool and linen fibres, animal and human hairs, an insect’s leg and grass debris. The bottle had been deposited upside down, and its cork may have been coated with beeswax, to which adhered a solid deposit of calcium phosphate, calcium carbonate and long-chain fatty acids and alcohols.
In view of the evidence of oxidation and fungal decomposition, it is urged that any archaeologists who unearth such objects have their contents analysed as soon as possible.