Tackling the perplexing problems of cleaning lacquered masterpieces
Furniture made and decorated in the Far East is often treated by lacquering and its conservation and preservation in museums for many years poses problems of cleaning.
The basic lacquer used for Japanese works of art contains urushiol, a catechol
derived from the sap of the tree Rhus verniciflua, which is hardened by the enzyme
laccase. The lacquer is initially hard and resistant to moisture and organic
solvents, but if exposed to low humidity conditions it loses some water and becomes
brittle and susceptible to attack by water and atmospheric oxygen.
In Chemistry World for September, Sarah Houlton has described some of the problems
faced by museum conservators when called upon to clean objects with a lacquer
finish, with special reference to the Mazarin chest, made in Japan 350 years
ago and now in the collection of the Victoria and Albert Museum in London. Degradation
caused by prolonged exposure to light means that application of tap water can
blanch the surface and diminish the characteristic gloss of the lacquer.
Photodamaged lacquer becomes more polar, and attracts more polar dirt, requiring
in turn increasingly polar solvents to remove soiling from the hydrophilic surface.
The application of a varnish layer to restore the surface has the effect of bringing
yellowing with age, and the use of solvents to remove the varnish may damage
the lacquer layer beneath the surface.
If removal of a surface stain is required, a polar solvent should be applied.
If there are penetrating cracks in the lacquer layer the cleaning solvent may
be trapped within them, and this may bring discoloration or even delamination.
Hydrocarbons usually do not damage lacquer, and they are effective in removing
waxes and oils.
Nevertheless, lacquering is a complex process, involving the application and
drying of many thin layers. Typically, inorganic pigments such as mercuric sulphide
or iron oxide are added at some stage to provide a pattern, and these must not
be disturbed in the cleaning process.
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