The price of trying to keep the planet clean
A commentary by Rebecca Renner published in Science for 10 December 2004 draws attention to the menace posed today by products based on perfluorinated chemicals that are designed to protector our domestic furnishings from staining.
Fluorinated stain protecters are widely used in the home to guard fabrics and
clothing from being ruined by spilt food products. The protectors consist of
fluorinated surfactants chemically bound to polymers. Most of these surfactants
do not travel far in the environment, but their volatile precursors, which are
fluorotelomer alcohols, do travel and degrade into perfluorocarboxylates. These
degradation products are being detected in increasing concentrations in seals
and polar bears in the Arctic and dolphins in mid-Atlantic.
The volatile precursors of stain protectors are able to travel thousands of miles
in atmospheric air currents and then react with oxygen to produce stable perfluorocarboxylates.
Concentrations of the final products are said to be doubling in Arctic animals
every four to 10 years. The alcohols concerned are released into the atmosphere
during both the manufacture of the surfactants and the application of the stain
protectors.
In another study in the same issue of the journal, Paul Webster reports that
indigenous people living in the Arctic are exposed to pesticides, heavy metals
and industrial compounds, with uncertain effects on health. Breast milk and maternal
blood samples have shown high concentrations of hexachlorobenzene, hexachlorocyclohexane,
dioxins, dicophane, oxychlordane, toxaphene, brominated flame retardants, mercury,
cadmium and lead. The highest levels occur where the local population eats large
amounts of marine mammals and fish. Such products may be linked to reproductive
effects such as stillbirths, birth defects, low birth weight and spontaneous
abortions. Exposure to lead or to polychlorobiphenyls apparently reduces the
numbers of male births in the Arctic. Further close investigations are urgently
called for.
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